I am looking to create a powershell script to create new AD accounts and then store the account and password in the Password vault. I see there are cmdlets for Remote Desktop, but there seen to not fit for Password vault. Is there a way to automate with Password Vault?
No, It has only been implemented in Remote Destkop Manager, but since they can connect to the same data sources it means that you need a single license of RDM to allow you to use Powershell scripting even against a PVM data source.
Our Marketing department will gladly work with you to get you an inexpensive license to that end. Just contact them at email@example.com to get the process started.